Cutts, P
1988
Low-Temperature C-13 Magnetic Resonance 8. Chemical Shielding Anisotropy of Olefinic Carbons
Orendt, A.M.; Facelli, J.C.; Beeler, A.J.; Reuter, K.; Horton, W.J.; Cutts, P.; Grant, D.M. and Michl, J.
American Chemical Society, 110, 3386, 1988. Funded by US Department of Energy.
The principal values of the C-13 NMR shielding tensor were measured at cryogenic temperatures for a series of olefinic carbons, including methyl-substituted ethylenes, 1-methyl- and 1,2-dimethylcycloalkenes, methylenecycloalkanes, and bicyclo (n,m.0) alkenes. Information on the orientation of the principal axes was obtained from ab initio calculations of the chemical shielding tensor using the IGLO (individual gauge for localized orbitals) method. The results for several compounds with unusual principal values of the shielding tensor were analyzed in terms of the bond contributions in the principal axis system.
Cutts, P
1988
Low-Temperature C-13 Magnetic Resonance 8. Chemical Shielding Anisotropy of Olefinic Carbons
Orendt, A.M.; Facelli, J.C.; Beeler, A.J.; Reuter, K.; Horton, W.J.; Cutts, P.; Grant, D.M. and Michl, J.
American Chemical Society, 110, 3386, 1988. Funded by US Department of Energy.
The principal values of the C-13 NMR shielding tensor were measured at cryogenic temperatures for a series of olefinic carbons, including methyl-substituted ethylenes, 1-methyl- and 1,2-dimethylcycloalkenes, methylenecycloalkanes, and bicyclo (n,m.0) alkenes. Information on the orientation of the principal axes was obtained from ab initio calculations of the chemical shielding tensor using the IGLO (individual gauge for localized orbitals) method. The results for several compounds with unusual principal values of the shielding tensor were analyzed in terms of the bond contributions in the principal axis system.