Bateman, KJ
1994
Bateman, K.J.; Germane, G.J.; Smoot, L.D. and Eatough, C.N.
Energy & Fuels, 1994 (in press). Funded by US Department of Energy/Morgantown Energy Technology Center and ACERC.
A study was undertaken to design, construct, characterize, and demonstrate a new facility for determination of reaction rates of large coal particles at elevated pressures. A cantilever balance attachment (CBA) was designed, fabricated, and utilized in conjunction with the existing High Pressure Controlled Profile (HPCP) reactor. Large particle (8mm diameter) combustion experiments of Utah HVBB coal at both atmospheric and elevated pressures were performed to demonstrate the facility's capabilities. Measurements were obtained of particle mass loss rate and surface temperature coupled with a video record for visual observation.
Bateman, K.J.; Smoot, L.D.; Germane, G.J.; Blackham, A.U. and Eatough, C.N.
Fuel, 1994 (in press). Funded by US Department of Energy/Morgantown Energy Technology Center and ACERC.
Mass loss and burnout ties of large (five and eight millimeter diameter) char particles at pressures between 101 to 760 kPa have been measured in a newly designed and constructed high-pressure reactor. A cantilever balance attachment was fitted to the reactor to measure instantaneous particle mass while an optical pyrometer measured particle temperature continuously. The process was also videotaped at 1/30 s frame speed. Sixty-two combustion experiments produced burning and oxidation times for two sizes of Utah bituminous (HVBB) coal and North Dakota Lignite (L) at 101, 507, 760 kPa total pressure. The reactor air temperatures were about 900 or 1200 K while the airflow Reynolds Number was varied by a factor of two. Coal particles were placed in a platinum-wire basket inside the reactor at the end of the balance beam. The oxidation process was recorded by computer and on videotape, while continuous char oxidation rates were measured to burnout. An ash layer accumulated around the particles, and receded as the char was consumed. In all of the tests, including the elevated pressure tests, a linear decrease in the cube root of char mass with time was observed during char oxidation until near the end of burnout. Changes in air velocity had little effect on oxidation times while either increasing gas temperature or increasing pressure from 101 kPa to 507 kPa reduced oxidation times by about one-quarter. Further increase in pressure caused no further reduction in burn time. Pairs of nearly equally sized particles of coal had oxidation times similar to single particles that had a mass equal to the sum of the pairs.